Synthesis of gem-difluoromethylenated spiro-γ-butyrolactones by employing PhSCF<inf>2</inf>Si(CH<inf>3</inf>)<inf>3</inf>as a gem-difluoromethylenating agent
PhSCF2TMS was utilized as a useful gem-difluoromethylene building block for the synthesis of gem-difluoromethylenated spiro-γ-butyrolactones. The radical cyclization of γ-alkenyl- γ-gem-difluoro(phenylsulfanyl)methyl-γ-butyrolactones provided gem-difluoromethylenated spiro-γ-butyrolactones. PhSCF2TM...
محفوظ في:
المؤلفون الرئيسيون: | Adisak Chatupheeraphat, Darunee Soorukram, Chutima Kuhakarn, Patoomratana Tuchinda, Vichai Reutrakul, Chaveng Pakawatchai, Saowanit Saithong, Manat Pohmakotr |
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مؤلفون آخرون: | Mahidol University |
التنسيق: | مقال |
منشور في: |
2018
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الموضوعات: | |
الوصول للمادة أونلاين: | https://repository.li.mahidol.ac.th/handle/123456789/31510 |
الوسوم: |
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مواد مشابهة
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Synthesis of gem -difluoromethylenated compounds employing α,α-difluoro-α-phenylsulfanyl-α-trimethylsilylmethane (PhSCF<inf>2</inf>SiMe<inf>3</inf>) as a gem -difluoromethylene building block
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منشور في: (2018) -
Stereoselective nucleophilic addition of PhSCF<inf>2</inf>SiMe<inf>3</inf> to chiral cyclic nitrones: Asymmetric synthesis of gem-difluoromethylenated polyhydroxypyrrolizidines and -indolizidines
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منشور في: (2018) -
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Diastereoselective Addition of PhSCF<inf>2</inf>SiMe<inf>3</inf>to Chiral N- tert-Butanesulfinyl Ketimines Derived from Isatins: Synthesis of Enantioenriched gem-Difluoromethylenated Spiro-pyrrolidinyl and Spiro-piperidinyl Oxindoles
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منشور في: (2023) -
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