Unprecedented Reactivity of AgSCF<inf>3</inf> with o-Isocyanobiaryls: Synthetic and Mechanistic Insight
The work reports an unusual reaction of o-isocyanobiaryls and AgSCF3, which led to the unexpected formation of 6-(trifluoromethyl)phenanthridines and o-biaryl isothiocyanates as products, instead of the expected 6-((trifluoromethyl)thio)phenanthridines. Density functional theory (DFT) calculations o...
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| Format: | Article |
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2023
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| Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/88264 |
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| Institution: | Mahidol University |