Crystal structures, spectro-structural correlation and structural pathways of eight [Cu(dpyam)<inf>2</inf>(NCO)][Y] complexes (dpyam = di-2-pyridylamine), Y = Br^-, CF<inf>3</inf>SO<inf>3</inf>^-, BF<inf>4</inf>^-· dpyam, Cl^-· 4H<inf>2</inf>O, NO<inf>3</inf>^-, PF<inf>6</inf>^-, ClO[...].

• Main Authors: Sujittra Youngme, Jaturong Phatchimkun, Unchulee Suksangpanya, Chaveng Pakawatchai, Narongsak Chaichit, Palangpon Kongsaeree, Jurek Krzystek, Brian Murphy
• Other Authors: Khon Kaen University
• Format: Article
• Published: 2018
• Subjects: Chemistry; Materials Science
• Online Access: https://repository.li.mahidol.ac.th/handle/123456789/24367
• Institution: Mahidol University

The crystal structures of eight new [Cu(dpyam)2(NCO)][Y] complexes which Y = Br-(1), CF3SO3-(2), BF4-· dpyam (3), Cl-· 4H2O (4), NO3-(5), PF6-(6), ClO4-(7) and BPh4-(8), respectively have been determined by X-ray crystallography. Five of the complexes, 1-5 (τ = 0.09-0.30) have a CuN4N′ chromophore w...