Asymmetric synthesis of gem -difluoromethylenated linear triquinanes via cascade gem -difluoroalkyl radical cyclization

• Main Authors: Watcharaporn Thaharn, Darunee Soorukram, Chutima Kuhakarn, Patoomratana Tuchinda, Chaveng Pakawatchai, Saowanit Saithong, Vichai Reutrakul, Manat Pohmakotr
• 其他作者: Mahidol University
• 格式: Article
• 出版: 2018
• 主題: Chemistry
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/35760

© 2014 American Chemical Society. An asymmetric synthesis of gem-difluoromethylenated linear triquinanes is described exploiting the synthetic utilities of PhSCF<inf>2</inf>TMS (5) as a "^•CF<inf>2</inf>^- building block. The s...