Synthesis of gem-difluoromethylenated spiro-γ-butyrolactones by employing PhSCF<inf>2</inf>Si(CH<inf>3</inf>)<inf>3</inf>as a gem-difluoromethylenating agent

Synthesis of gem-difluoromethylenated spiro-γ-butyrolactones by employing PhSCF<inf>2</inf>Si(CH<inf>3</inf>)<inf>3</inf>as a gem-difluoromethylenating agent

PhSCF2TMS was utilized as a useful gem-difluoromethylene building block for the synthesis of gem-difluoromethylenated spiro-γ-butyrolactones. The radical cyclization of γ-alkenyl- γ-gem-difluoro(phenylsulfanyl)methyl-γ-butyrolactones provided gem-difluoromethylenated spiro-γ-butyrolactones. PhSCF2TM...

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Bibliographic Details
Main Authors: Adisak Chatupheeraphat, Darunee Soorukram, Chutima Kuhakarn, Patoomratana Tuchinda, Vichai Reutrakul, Chaveng Pakawatchai, Saowanit Saithong, Manat Pohmakotr
Other Authors: Mahidol University
Format: Article
Published: 2018
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/31510
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Institution: Mahidol University

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https://repository.li.mahidol.ac.th/handle/123456789/31510

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