Dibenzopleiadiene-embeded polyaromatics: Via [4 + 3] annulative decarbonylation/decarboxylation

• المؤلفون الرئيسيون: Kritchasorn Kantarod, Thanapat Worakul, Darunee Soorukram, Chutima Kuhakarn, Vichai Reutrakul, Panida Surawatanawong, Worawat Wattanathana, Pawaret Leowanawat
• مؤلفون آخرون: Kasetsart University
• التنسيق: مقال
• منشور في: 2022
• الموضوعات: Chemistry
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/76621

A novel strategy is developed for the synthesis of dibenzopleiadiene-embedded polycyclic aromatic hydrocarbons from 1,8-naphthalic anhydride derivatives and cyclic diaryliodonium salts through a palladium-catalyzed cascade [4 + 3] decarbonylative/decarboxylative annulation. The mechanism of the reac...