Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>

Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Asymmetric synthesis of trifluoromethylated derivative of ent-fragransin C 1 was reported. The installation of contiguous stereochemistries across the tetrahydrofuran scaffold was achieved through stereocontrolled conjugate addition, aldol rea...

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Main Authors: Sasirome Racochote, Manat Pohmakotr, Chutima Kuhakarn, Pawaret Leowanawat, Vichai Reutrakul, Darunee Soorukram
Other Authors: Mahidol University
Format: Article
Published: 2020
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/50573
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spelling th-mahidol.505732020-01-27T15:13:54Z Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf> Sasirome Racochote Manat Pohmakotr Chutima Kuhakarn Pawaret Leowanawat Vichai Reutrakul Darunee Soorukram Mahidol University Chemistry © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Asymmetric synthesis of trifluoromethylated derivative of ent-fragransin C 1 was reported. The installation of contiguous stereochemistries across the tetrahydrofuran scaffold was achieved through stereocontrolled conjugate addition, aldol reaction, and a protection-free intramolecular C-O bond formation (furan ring formation) via chemoselective generation of the benzylic carbocation. 2020-01-27T08:13:54Z 2020-01-27T08:13:54Z 2019-03-31 Article European Journal of Organic Chemistry. Vol.2019, No.12 (2019), 2212-2223 10.1002/ejoc.201801676 10990690 1434193X 2-s2.0-85060334645 https://repository.li.mahidol.ac.th/handle/123456789/50573 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85060334645&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemistry
spellingShingle Chemistry
Sasirome Racochote
Manat Pohmakotr
Chutima Kuhakarn
Pawaret Leowanawat
Vichai Reutrakul
Darunee Soorukram
Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>
description © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Asymmetric synthesis of trifluoromethylated derivative of ent-fragransin C 1 was reported. The installation of contiguous stereochemistries across the tetrahydrofuran scaffold was achieved through stereocontrolled conjugate addition, aldol reaction, and a protection-free intramolecular C-O bond formation (furan ring formation) via chemoselective generation of the benzylic carbocation.
author2 Mahidol University
author_facet Mahidol University
Sasirome Racochote
Manat Pohmakotr
Chutima Kuhakarn
Pawaret Leowanawat
Vichai Reutrakul
Darunee Soorukram
format Article
author Sasirome Racochote
Manat Pohmakotr
Chutima Kuhakarn
Pawaret Leowanawat
Vichai Reutrakul
Darunee Soorukram
author_sort Sasirome Racochote
title Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>
title_short Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>
title_full Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>
title_fullStr Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>
title_full_unstemmed Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>
title_sort asymmetric synthesis of trifluoromethylated ent-fragransin c <inf>1</inf>
publishDate 2020
url https://repository.li.mahidol.ac.th/handle/123456789/50573
_version_ 1763487458426617856

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