Intramolecular acylation of α-sulfinyl carbanion a new general route to 5-methylene-2-cyclopentenones

A convenient synthesis of 5-methylene-2-cyclopentenones including Methylenomycin B involving the intramolecular acylation of α-sulfinyl carbanion followed by methylation and pyrolysis is described. © 1984.

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Bibliographic Details
Main Authors: Manat Pohmakotr, Sirirat Chancharunee
Other Authors: Mahidol University
Format: Article
Published: 2018
Subjects:
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/30584
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Institution: Mahidol University