Intramolecular acylation of α-sulfinyl carbanions with masked α,β-unsaturated esters: a general strategy to 5-alkylidene-2-cyclopentenones

A general method for the preparation of 5-alkylidene-2-cyclopentenones and their 2-phenylsulfanyl substituted derivatives, involving the intramolecular acylation of α-sulfinyl carbanions with cyclopentadiene-α,β-unsaturated esters as the key reaction followed by flash vacuum pyrolysis, is described....

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Bibliographic Details
Main Authors: Manat Pohmakotr, Sirinporn Thamapipol, Patoomratana Tuchinda, Vichai Reutrakul
Other Authors: Mahidol University
Format: Article
Published: 2018
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Online Access:https://repository.li.mahidol.ac.th/handle/123456789/24246
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Institution: Mahidol University