Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones
(Chemical Equation Presented) The reaction of masked 5-alkylidene-2- cyclopentenones with aldehydes catalyzed by tributylphosphine in the presence of phenol provided the corresponding Morita-Baylis-Hillman adducts, which were subjected to flash vacuum pyrolysis to afford 5-alkylidene-2-(hydroxyalkyl...
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2018
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在線閱讀: | https://repository.li.mahidol.ac.th/handle/123456789/24344 |
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