Synthesis of aryl α-keto esters via the rearrangement of aryl cyanohydrin carbonate esters

A facile synthesis of aryl α-keto esters is reported involving the rearrangement of aryl cyanohydrin carbonate esters induced by the α-carbanion to the nitrile group generated by LDA. However, under similar conditions, an o-benzyloxycyanohydrin carbonate ester rearranged via a domino reaction leadin...

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Bibliographic Details
Main Authors: Nopporn Thasana, Vilailak Prachyawarakorn, Sopchok Tontoolarug, Somsak Ruchirawat
Other Authors: Chulabhorn Research Institute
Format: Article
Published: 2018
Subjects:
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/20770
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