A general synthetic route to 1-azabicyclo[m.n.0]alkenes via cyclisation based on α-sulfinyl carbanions

• المؤلفون الرئيسيون: Manat Pohmakotr, Pornthep Numechai, Saisuree Prateeptongkum, Patoomratana Tuchinda, Vichai Reutrakul
• مؤلفون آخرون: Mahidol University
• التنسيق: مقال
• منشور في: 2018
• الموضوعات: Biochemistry, Genetics and Molecular Biology; Chemistry
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/20684

A general synthetic route to 1-azabicyclo[m.n.0]alkenes via cyclisation based on α-sulfinyl carbanions was presented. The intramolecular nucleophillic addition of α-sulfinyl carbanions afforded 1-azabicyclo[m.n.0]alkenes in good yields. It is reported that the developed strategy should provide a gen...