Synthesis of gem -difluoromethylenated polycyclic cage compounds

• Main Authors: Chonticha Masusai, Darunee Soorukram, Chutima Kuhakarn, Patoomratana Tuchinda, Chaveng Pakawatchai, Saowanit Saithong, Vichai Reutrakul, Manat Pohmakotr
• 其他作者: Mahidol University
• 格式: Article
• 出版: 2018
• 主題: Chemistry
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/35758

© 2015 American Chemical Society. The synthesis of gem-difluoromethylenated polycyclic cage compounds, utilizing PhSCF2SiMe3 as a gem-difluoromethylene building block, is described. The fluoride-catalyzed nucleophilic addition of PhSCF2SiMe3 to both maleic anhydride-cyclopentadiene and maleic anhydr...