Nucleophilic gem-difluoro(phenylsulfanyl)methylation of carbonyl compounds with PhSCF<inf>2</inf>H in the presence of a phosphazene as a base
Direct nucleophilic gem-difluoro(phenylsulfanyl)methylation of carbonyl compounds has been achieved by use of difluoro(phenylsulfanyl)methane (PhSCF2H) and the phosphazene base P4-tBu in THF. Non-enolizable aldehydes and ketones are suitable substrates to undergo nucleophilic gem-difluoro(phenylsulf...
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| Main Authors: | , , , , |
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| 格式: | Article |
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2018
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| 在線閱讀: | https://repository.li.mahidol.ac.th/handle/123456789/33638 |
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| 機構: | Mahidol University |