Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol

• المؤلفون الرئيسيون: Nopporn Thasana, Somchai Pisutjaroenpong, Somsak Ruchirawat
• مؤلفون آخرون: Chulabhorn Research Institute
• التنسيق: مقال
• منشور في: 2018
• الموضوعات: Chemistry
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/23164

The application of directed orthometallation (DoM), Fries rearrangement and transmetallation followed by allylation and cyclization is reported for the conversion of biphenol to binaphthol as a means for the synthesis of diospyrol. Furthermore, the same transformation can be accomplished by the reac...