Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol

The application of directed orthometallation (DoM), Fries rearrangement and transmetallation followed by allylation and cyclization is reported for the conversion of biphenol to binaphthol as a means for the synthesis of diospyrol. Furthermore, the same transformation can be accomplished by the reac...

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Bibliographic Details
Main Authors: Nopporn Thasana, Somchai Pisutjaroenpong, Somsak Ruchirawat
Other Authors: Chulabhorn Research Institute
Format: Article
Published: 2018
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Online Access:https://repository.li.mahidol.ac.th/handle/123456789/23164
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Institution: Mahidol University