Destannylative acylation of 1-(tributylstannyl)-1-(phenylsulfonyl)-cyclopropane and -ethene.
The reaction of α-stannyl sulfones 1 and 2 with acyl chlorides in refluxing toluene, leading to 1-acyl-1-(phenylsulfonyl)cyclopropanes 3 and the labile 1-acyl-1-(phenylsulfonyl)ethenes 4, is described. © 1993.
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2018
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