Destannylative pummerer-type rearrangement of 1-(phenylsulfinyl)-1-(tributylstannyl)cyclopropane
1-(Phenylsulfinyl)-1-(tributylstannyl)cyclopropane on treatment with acyl chlorides or alkyl chloroformate in refluxing dichloromethane afforded 1-acyloxy-1-phenylsulfenyl- and 1-alkoxycarbonyloxy-1-phenylsulfenylcyclopropanes, respectively. The reaction involves the Pummerer-type rearrangement with...
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2018
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在線閱讀: | https://repository.li.mahidol.ac.th/handle/123456789/15718 |
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機構: | Mahidol University |