Destannylative Pummerer-type rearrangement of 1-(tributylstannyl)-1-(phenylsulfinyl)- cyclopropane and -ethene.

• Main Authors: Manat Pohmakotr, Srisamorn Sithikanchanakul, Sujitra Khosavanna
• 其他作者: Mahidol University
• 格式: Article
• 出版: 2018
• 主題: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/22533

1-(Tributylstannyl)-1-(phenylsulfinyl)-cyclopropane and -ethene were found to react with acyl chlorides to provide the corresponding 1-acyloxy-1-(phenylthio)-cyclopropanes and -ethenes. The reaction involves the Pummerer-type rearrangement with loss of the tributylstannyl group. © 1993.