Destannylative Pummerer-type rearrangement of 1-(tributylstannyl)-1-(phenylsulfinyl)- cyclopropane and -ethene.

• المؤلفون الرئيسيون: Manat Pohmakotr, Srisamorn Sithikanchanakul, Sujitra Khosavanna
• مؤلفون آخرون: Mahidol University
• التنسيق: مقال
• منشور في: 2018
• الموضوعات: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/22533

1-(Tributylstannyl)-1-(phenylsulfinyl)-cyclopropane and -ethene were found to react with acyl chlorides to provide the corresponding 1-acyloxy-1-(phenylthio)-cyclopropanes and -ethenes. The reaction involves the Pummerer-type rearrangement with loss of the tributylstannyl group. © 1993.