The application of the Baker-Venkataraman rearrangement to the synthesis of benz[b]indeno[2,1-e]pyran-10,11-dione

• Main Authors: Nopporn Thasana, Somsak Ruchirawat
• 其他作者: Chulabhorn Research Institute
• 格式: Article
• 出版: 2018
• 主題: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/20107
• 機構: Mahidol University

A tetracyclic benzocyclopentabenzopyran-4-one was synthesized via a domino reaction involving an initial aroyl transfer as in the Baker-Venkataraman rearrangement. The derived 1,3 diketone underwent the intramolecular acylation followed by cyclization to give the product. © 2002 Elsevier Science Ltd...