Five-coordinate copper(II) complexes: Crystal structures, spectroscopic properties and new extended structural pathways of [Cu(chelate)<inf>2</inf>X]Y, where chelate = dpyam, phen and bipy; X = pseudohalide ligands

• Main Authors: Sujittra Youngme, Pongthipun Phuengphai, Chaveng Pakawatchai, Palangpon Kongsaeree, Narongsak Chaichit
• Other Authors: Khon Kaen University
• Format: Article
• Published: 2018
• Subjects: Biochemistry, Genetics and Molecular Biology
• Online Access: https://repository.li.mahidol.ac.th/handle/123456789/18918
• Institution: Mahidol University

The crystal structures of four distortion isomers of the [Cu(chelate)2 X]+cation, where chelate = 2,2-bipyridine (bipy), 1,10-phenanthroline (phen) and di-2-pyridylamine (dpyam), X = a pseudohalide ligand (NCO, NCS, N3 and C2N3), have been compared by scatterplot analysis with 25 [Cu(chelate)2 X]Y c...