Efficient synthesis of malonate functionalized chiral phosphapalladacycles and their catalytic evaluation in asymmetric hydrophosphination of chalcone

• المؤلفون الرئيسيون: Li, Xi-Rui, Chen, Yu, Pang, Benjamin Piaoxiang, Tan, Jaeyu, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Engineering::Chemical engineering; Catalytic; Hydrophosphination
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/144670

Four chiral phosphapalladacycle complexes functionalized with the malonate moiety at the chiral carbon have been synthesized via a consecutive asymmetric hydrophosphination and cyclometallation protocol. High conversions were achieved in the P–H addition reaction, which was itself catalyzed by a pho...