Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines

• المؤلفون الرئيسيون: Pullarkat, Sumod A., Xu, Chang, Gan, Kennard Jun Hao, Hennersdorf, Felix, Li, Yongxin, Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/101494; http://hdl.handle.net/10220/13698

A chiral palladacycle-promoted enantioselective asymmetric hydrophosphination of substituted methylidenemalonate esters using diphenylphosphine that provides direct access to chiral tertiary phosphines is reported. Screening of three easily accessible C,N and C,P palladacycles as catalysts for this...