Charge neutral halogen bonding tetradentate-iodotriazole macrocycles capable of anion recognition and sensing in highly competitive aqueous media

• المؤلفون الرئيسيون: Thanthapatra Bunchuay, Kajjana Boonpalit, Andrew Docker, Araya Ruengsuk, Jonggol Tantirungrotechai, Mongkol Sukwattanasinitt, Panida Surawatanawong, Paul D. Beer
• مؤلفون آخرون: Chulalongkorn University
• التنسيق: مقال
• منشور في: 2022
• الموضوعات: Chemical Engineering; Chemistry; Materials Science
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/76495
• المؤسسة: Mahidol University

A series of neutral tetradentate halogen bonding (XB) macrocycles, comprising of two bis-iodotriazole XB donors were synthesised in 60-70% yields via a stepwise CuAAC-mediated cyclisation strategy. Extensive 1H NMR anion titration experiments reveal halide binding affinities are critically dependent...