Dispersed Ru nanoclusters transformed from a grafted trinuclear Ru complex on SiO<inf>2</inf>for selective alcohol oxidation

• المؤلفون الرئيسيون: Satoshi Muratsugu, Min Hwee Lim, Takahiro Itoh, Wipavee Thumrongpatanaraks, Mio Kondo, Shigeyuki Masaoka, T. S. Andy Hor, Mizuki Tada
• مؤلفون آخرون: National Institutes of Natural Sciences - Institute for Molecular Science
• التنسيق: مقال
• منشور في: 2018
• الموضوعات: Chemistry
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/31512
• المؤسسة: Mahidol University

Ru nanoclusters (average diameter = 1.3 ± 0.3 nm) were successfully prepared by using a Ru3cluster Ru3O(CH3COO)6(H2O)3·(CH3COO) grafted on a pyridine-functionalized SiO2surface. The pyridine moiety dispersed on the SiO2surface spread the Ru3cluster, controlling its surface density, and the nanoclust...