PhI(OAc)<inf>2</inf>/KI mediated 1,2-acetoxysulfenylation of alkenes: Facile synthesis of β-acetoxysulfides

• Main Authors: Charoensak Muangkaew, Praewpan Katrun, Patcharaphon Kanchanarugee, Manat Pohmakotr, Vichai Reutrakul, Darunee Soorukram, Thaworn Jaipetch, Chutima Kuhakarn
• 其他作者: Mahidol University
• 格式: Article
• 出版: 2018
• 主題: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/31187

A convenient method for 1,2-acetoxysulfenylation of alkenes using disulfide promoted by (diacetoxyiodo)benzene (PhI(OAc)2, DIB)/KI was developed. The reaction is highly regioselective for styrene derivatives while aliphatic alkenes lead to a mixture of two regioisomers. © 2013 Elsevier Ltd. All righ...