Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones
Alkylation of lithio fluoromethyl phenyl sulfoxide 2 gave the alkylated products in high yields. Pyrolysis of the products led to vinyl fluorides in excellent yields. The reaction of 2 with carbonyl compounds led to the corresponding β-hydroxy-α-fluoromethyl phenyl sulfoxides. Pyrolysis of some of t...
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th-mahidol.304472018-10-12T14:37:41Z Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones Vichai Reutrakul Vatcharin Rukachaisirikul Mahidol University Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics Alkylation of lithio fluoromethyl phenyl sulfoxide 2 gave the alkylated products in high yields. Pyrolysis of the products led to vinyl fluorides in excellent yields. The reaction of 2 with carbonyl compounds led to the corresponding β-hydroxy-α-fluoromethyl phenyl sulfoxides. Pyrolysis of some of the sulfoxides gave fluoromethylketones in moderate yields. © 1983. 2018-10-12T07:34:05Z 2018-10-12T07:34:05Z 1983-01-01 Article Tetrahedron Letters. Vol.24, No.7 (1983), 725-728 10.1016/S0040-4039(00)81509-9 00404039 2-s2.0-0000086269 https://repository.li.mahidol.ac.th/handle/123456789/30447 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0000086269&origin=inward |
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Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics |
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Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics Vichai Reutrakul Vatcharin Rukachaisirikul Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| description |
Alkylation of lithio fluoromethyl phenyl sulfoxide 2 gave the alkylated products in high yields. Pyrolysis of the products led to vinyl fluorides in excellent yields. The reaction of 2 with carbonyl compounds led to the corresponding β-hydroxy-α-fluoromethyl phenyl sulfoxides. Pyrolysis of some of the sulfoxides gave fluoromethylketones in moderate yields. © 1983. |
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Mahidol University |
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Mahidol University Vichai Reutrakul Vatcharin Rukachaisirikul |
| format |
Article |
| author |
Vichai Reutrakul Vatcharin Rukachaisirikul |
| author_sort |
Vichai Reutrakul |
| title |
Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| title_short |
Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| title_full |
Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| title_fullStr |
Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| title_full_unstemmed |
Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| title_sort |
fluoromethyl phenyl sulfoxide: highly convenient syntheses of vinyl fluorides and fluoromethylketones |
| publishDate |
2018 |
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https://repository.li.mahidol.ac.th/handle/123456789/30447 |
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1763492109254393856 |