Destannylative pummerer-type rearrangement of 1-(phenylsulfinyl)-1-(tributylstannyl)cyclopropane

• المؤلفون الرئيسيون: Manat Pohmakotr, Srisamorn Sithikanchanakul
• مؤلفون آخرون: Mahidol University
• التنسيق: مقال
• منشور في: 2018
• الموضوعات: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• الوصول للمادة أونلاين: https://repository.li.mahidol.ac.th/handle/123456789/15718

1-(Phenylsulfinyl)-1-(tributylstannyl)cyclopropane on treatment with acyl chlorides or alkyl chloroformate in refluxing dichloromethane afforded 1-acyloxy-1-phenylsulfenyl- and 1-alkoxycarbonyloxy-1-phenylsulfenylcyclopropanes, respectively. The reaction involves the Pummerer-type rearrangement with loss of tributylstannyl group. © 1989.