Palladium-mediated heck-type reactions of [(Bromodifluoromethyl)sulfonyl] benzene: Synthesis of α-alkenyl- and α-heteroaryl-substituted α,α-difluoromethyl phenyl sulfones

Palladium-catalyzed Heck-type reactions of [(bromodifluoromethyl)sulfonyl] benzene (1) with styrene derivatives and heteroaromatic compounds successfully gave α-alkenyl- and α-heteroaryl-substituted α,α- difluoromethyl phenyl sulfones, respectively. Palladium-catalyzed Heck-type reactions of [(bromo...

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Main Authors: Nakin Surapanich, Chutima Kuhakarn, Manat Pohmakotr, Vichai Reutrakul
其他作者: Mahidol University
格式: Article
出版: 2018
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在線閱讀:https://repository.li.mahidol.ac.th/handle/123456789/13941
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總結:Palladium-catalyzed Heck-type reactions of [(bromodifluoromethyl)sulfonyl] benzene (1) with styrene derivatives and heteroaromatic compounds successfully gave α-alkenyl- and α-heteroaryl-substituted α,α- difluoromethyl phenyl sulfones, respectively. Palladium-catalyzed Heck-type reactions of [(bromodifluoromethyl)sulfonyl] benzene (1) are reported. Both styrene derivatives and heteroaromatic compounds gave PhSO 2 CF 2 -substituted products in moderate to good yields. © 2012 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.