Unsaturated Mn(II)-Centered [Mn(BDC)]<inf>n</inf> Metal-Organic Framework with Strong Water Binding Ability and Its Potential for Dehydration of an Ethanol/Water Mixture

• Main Authors: Kanyaporn Adpakpang, Warat Pratanpornlerd, Panyapat Ponchai, Wararat Tranganphaibul, Sutarat Thongratkaew, Kajornsak Faungnawakij, Satoshi Horike, Theeranun Siritanon, Apinpus Rujiwatra, Makoto Ogawa, Sareeya Bureekaew
• 格式: 雜誌
• 出版: 2018
• 主題: Chemistry
• 在線閱讀: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85055093125&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/62623

Copyright © 2018 American Chemical Society. An unsaturated Mn(II)-centered metal-organic framework was synthesized. The presence of an unsaturated Mn(II) center, together with a guest-responsive structural changing feature, plays a crucial role for strong binding with water, leading to its potential...