Phenanthrene synthesis via chromium-catalyzed annulation of 2-biaryl grignard reagents and alkynes
A chromium/2,2′-bipyridine-catalyzed annulation reaction of 2-biarylmagnesium reagents with alkynes is reported. The reaction is applicable to a variety of aryl- and/or alkyl-substituted internal alkynes as well as 2-biaryl and related Grignard reagents, thus affording phenanthrene derivatives in mo...
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| Main Authors: | , |
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| 格式: | Article |
| 語言: | English |
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2019
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| 在線閱讀: | https://hdl.handle.net/10356/90303 http://hdl.handle.net/10220/48492 |
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