Regio-and stereoselective C(sp²)-H acylation of enamides with aldehydes : via transition-metal-free photoredox catalysis

• Main Authors: Zhao, Kai, Zhang, Xiao-Chen, Tao, Ji-Yu, Wu, Xian-Dan, Wu, Jia-Xu, Li, Wei-Ming, Zhu, Tong-Hao, Loh, Teck-Peng
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Science::Chemistry; Enamides; Catalysis
• 在線閱讀: https://hdl.handle.net/10356/155611
• 機構: Nanyang Technological University

A straightforward and efficient C(sp2)-H acylation of enamides with aldehydes via transition-metal-free photoredox catalysis is demonstrated. The transformation proceeded smoothly without resorting to expensive and potentially toxic iridium or ruthenium polypyridyl-based photocatalysts under mild co...