Germylone-bridged bimetallic Ir and Rh complexes

• المؤلفون الرئيسيون: Su, Bochao, Ota, Kei, Li, Yongxin, Kinjo, Rei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2021
• الموضوعات: Science::Chemistry; Germylone; Bimetallic Complexes
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/146216

The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge...