E-H (E = B, Si, C) Bond activation by tuning structural and electronic properties of phosphenium cations

• المؤلفون الرئيسيون: Đorđević, Nemanja, Ganguly, Rakesh, Petković, Milena, Vidović, Dragoslav
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Hydrogen Abstraction; Anions
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/142688
• المؤسسة: Nanyang Technological University

In this work, strategic enhancement of electrophilicity of phosphenium cations for the purpose of small-molecule activation was described. Our synthetic methodology for generation of novel two-coordinate phosphorus(III)-based compounds [{C6H4(MeN)2C}2C·PR]2+ ([2a]2+, R = NiPr2; [2b]2+, R = Ph) was b...