Sodium vanadium oxide : a new material for high-performance symmetric sodium-ion batteries

Room-temperature sodium-ion batteries have the potential to become the technology of choice for large-scale electrochemical energy storage because of the high sodium abundance and low costs. However, not many materials meet the performance requirements for practical applications. Here, we report a n...

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Main Authors: Hartung, Steffen, Bucher, Nicolas, Nair, Vivek Sahadevan, Ling, Cheah Yan, Wang, Yuxi, Hoster, Harry E., Srinivasan, Madhavi
其他作者: School of Materials Science & Engineering
格式: Article
語言:English
出版: 2014
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在線閱讀:https://hdl.handle.net/10356/105478
http://hdl.handle.net/10220/20694
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機構: Nanyang Technological University
語言: English
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總結:Room-temperature sodium-ion batteries have the potential to become the technology of choice for large-scale electrochemical energy storage because of the high sodium abundance and low costs. However, not many materials meet the performance requirements for practical applications. Here, we report a novel sodium-ion battery electrode material, Na2.55V6O16⋅0.6 H2O, that shows significant capacities and stabilities at high current rates up to 800 mA g−1. X-ray photoelectron spectroscopy measurements are carried out to better understand the underlying reactions. Moreover, due to the different oxidation states of vanadium, this material can also be employed in a symmetric full cell, which would decrease production costs even further. For these full cells, capacity and stability tests are conducted using various cathode:anode mass ratios.