The dithiolate-bridged diiron hexacarbonyl complex Na2[(μ-SCH2CH2COO)Fe(CO)3]2 as a water-soluble photoCORM

• Main Authors: Fan, Wai Yip, Poh, Hwa Tiong, Sim, Bai Ting, Chwee, Tsz Sian, Leong, Weng Kee
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2014
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• 在線閱讀: https://hdl.handle.net/10356/103104; http://hdl.handle.net/10220/24372
• 機構: Nanyang Technological University

The water-soluble dimercaptopropanoate-bridged diiron hexacarbonyl complex Na2[(μ-SCH2CH2COO)Fe(CO)3]2 has been prepared, and the X-ray crystal structure and infrared, UV–visible, and ESI spectra of the complex have been obtained. The complex is shown to behave as a photoCORM, whereby all six CO lig...