Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines

• Main Authors: Pullarkat, Sumod A., Xu, Chang, Gan, Kennard Jun Hao, Hennersdorf, Felix, Li, Yongxin, Leung, Pak-Hing
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2013
• 在線閱讀: https://hdl.handle.net/10356/101494; http://hdl.handle.net/10220/13698
• 機構: Nanyang Technological University

A chiral palladacycle-promoted enantioselective asymmetric hydrophosphination of substituted methylidenemalonate esters using diphenylphosphine that provides direct access to chiral tertiary phosphines is reported. Screening of three easily accessible C,N and C,P palladacycles as catalysts for this...