Bioinspired asymmetric synthesis of (-)-gymnothelignan v

• Main Authors: Darunee Soorukram, Manat Pohmakotr, Chutima Kuhakarn, Vichai Reutrakul
• 其他作者: Mahidol University
• 格式: Article
• 出版: 2019
• 主題: Chemistry
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/45500

© 2018 American Chemical Society. A bioinspired asymmetric total synthesis of a structurally unique subtype of lignan, namely, (-)-gymnothelignan V, was achieved. The key synthetic sequences involved reduction of the eupomatilone skeleton leading to (-)-gymnothelignan J followed by the formation of...