Vicinal dianions of diethyl α-aroylsuccinates: Preparation of functionalized-2,3-dihydrofurans and -furans, and diaxial 2,4-diaryl-3,7-dioxabicyclo[3.3.0]octanes

• Main Authors: Manat Pohmakotr, Arisara Issaree, Laddawan Sampaongoen, Patoomratana Tuchinda, Vichai Reutrakul
• 其他作者: Mahidol University
• 格式: Article
• 出版: 2018
• 主題: Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics
• 在線閱讀: https://repository.li.mahidol.ac.th/handle/123456789/20685

Vicinal dianions of diethyl α-aroylsuccinates react with aromatic aldehydes to provide functionalized 2,3-dihydrofurans as the major products together with γ-butyrolactones after treatment of the adducts obtained with a catalytic amount of p-toluenesulfonic acid in refluxing toluene. cis-2,3-Dihydro...