Reversible CO2 activation by an N-phosphinoamidinato digermyne

• المؤلف الرئيسي: Quek, Shina
• مؤلفون آخرون: So Cheuk Wai
• التنسيق: Thesis-Master by Research
• اللغة: English
• منشور في: Nanyang Technological University 2022
• الموضوعات: Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/160026
• المؤسسة: Nanyang Technological University

This thesis describes the synthesis of the N-phosphinoamidinato digermynes [LG̈e–G̈eL] (E = Ge, L = tBu2PNC(Ph)NAr, 5: Ar = 2,6-iPr2C6H3, 6: Ar = Ph) by the reduction of the corresponding chlorogermylenes with KC8. Compounds 5 and 6 underwent reversible oxidative addition with CO2 in toluene at room...